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Summary
Semi-final 1
| Rank | Name | Nation | Time |
| 1 | Shawn Crawford | USA | 10.07 |
| 2 | Justin Gatlin | USA | 10.09 |
| 3 | Aziz Zakari | GHA | 10.11 |
| 4 | Obadele Thompson | BAR | 10.22 |
| 5 | Mark Lewis-Francis | GBR | 10.28 |
| 6 | Michael Frater | JAM | 10.29 |
| 7 | Ronald Pognon | FRA | 10.32 |
| 8 | Uchenna Emedolu | NGR | 10.35 |
| Rank | Name | Nation | Time |
| 1 | Asafa Powell | JAM | 9.95 |
| 2 | Francis Obikwelu | POR | 9.97 |
| 3 | Maurice Greene | USA | 9.97 |
| 4 | Kim Collins | SKN | 10.02 |
| 5 | Jason Gardener | GBR | 10.12 |
| 6 | Leo Myles-Mills | GHA | 10.22 |
| 7 | Dwight Thomas | JAM | 10.28 |
| 8 | Vicente de Lima | BRA | 10.28 |