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Date: 17 August 2004
Summary
Semi-final 1
| Rank | Name | Nation | Time |
| 1 | Salim Iles | ALG | 49.13 |
| 2 | Duje Draganja | CRO | 49.14 |
| 3 | Ian Thorpe | AUS | 49.21 |
| 4 | Alexander Popov | RUS | 49.23 |
| 5 | George Bovell III | TTO | 49.53 |
| 6 | Peter Mankoc | SLO | 49.71 |
| 7 | Rolandas Gimbutis | LTU | 49.75 |
| 8 | Luis Rojas | VEN | 49.85 |
| Rank | Name | Nation | Time |
| 1 | Roland Schoeman | RSA | 48.39 |
| 2 | Pieter van den Hoogenband | NED | 48.55 |
| 3 | Filippo Magnini | ITA | 48.91 |
| 4 | Andrey Kapralov | RUS | 49.12 |
| 5 | Ryk Neethling | RSA | 49.18 |
| 6 | Frederick Bousquet | FRA | 49.25 |
| 7 | Romain Barnier | FRA | 49.63 |
| 8 | Torsten Spanneberg | GER | 49.88 |