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Dates: 10 August 2008-17 August 2008
Heats
Repechages
Semi-finals
Final
| Rank | Name | Nation | Time |
| 1 | Kirsten van der Kolk; Marit van Eupen | NED | 6:54.74 |
| 2 | Sanna Stén; Minna Nieminen | FIN | 6:56.03 |
| 3 | Melanie Kok; Tracy Cameron | CAN | 6:56.68 |
| 4 | Berit Carow; Marie-Louise Dräger | GER | 6:56.72 |
| 5 | Xu Dongxiang; Yu Hua | CHN | 7:01.90 |
| 6 | Khrysa Biskitzi; Alexandra Tsiavou | GRE | 7:04.61 |
| Final B | |||
| 7 | Katrin Olsen; Juliane Rasmussen | DEN | 7:06.94 |
| 8 | Amber Halliday; Marguerite Houston | AUS | 7:07.17 |
| 9 | Misaki Kumakura; Akiko Iwamoto | JPN | 7:08.49 |
| 10 | Renee Hykel; Jen Goldsack | USA | 7:09.02 |
| 11 | Hester Goodsell; Helen Casey | GBR | 7:11.24 |
| 12 | Yaima Velázquez; Ismaray Marrero | CUB | 7:20.07 |
| Final C | |||
| 13 | Gabriela Huerta; Lila Pérez-Rul | MEX | 7:17.21 |
| 14 | Alex White; Kirsten McCann | RSA | 7:20.49 |
| 15 | Camila Carvalho; Luciana Granato | BRA | 7:22.40 |
| 16 | Nataliya Voronova; Aleksandra Opachanova | KAZ | 7:32.36 |
| 17 | Ko Young-Eun; Ji Yoo-Jin | KOR | 7:39.46 |